Defining the Temperature Dependence of Strain Crystallization in Endurica

Crystallization requires the suppression of molecular mobility, which in natural rubber can happen either by reducing the temperature or by increasing the strain.  Crystallization of natural rubber can be extremely beneficial to durability.  Nonrelaxing conditions (ie R>0) can increase life by factors of more than 100!  So, what happens if you have both high mean strain and high temperature?

This was the question studied in 2019 by Ruellan et al.  They constructed Haigh diagrams for a filled natural rubber at 3 temperatures: 23 degC, 90 degC and 110 degC.  They completed a large experimental study using dumbbell shaped specimens with a matrix consisting of approximately 4 R ratios x 4 amplitudes x 3 temperatures = 48 conditions.  Their results show that the increase of fatigue life with increasing mean strain at constant amplitude disappears as temperature is increased.  In particular, notice how at 23 degC each life contour (shown in red) has a strongly defined minimum force amplitude that lies near the R=0 line.  Also notice how, at higher temperatures, the life contours start to reflect a decrease of life with increasing mean strain.

This interesting effect can easily by replicated in the Endurica fatigue solver by letting the strain crystallization effect depend on temperature.  The material definition we have used in this quick demo is given below in both the old hfi format and the new Katana json format.  I have highlighted in yellow those parts of the definition which reflect the temperature dependence.

In the material definition, we have reflected two behaviors:

  1. the increase of crack growth rate with temperature (ie the RC parameter), and
  2. the decrease of strain crystallization with temperature (ie the Mars-Fatemi exponential strain crystallization parameter FEXP).

We have plotted the resulting Haigh diagrams in the Endurica viewer, and directly overlaid Ruellan’s results for comparison.  Although the x and y scales in Ruellan’s results are shown in terms of total specimen force and ours are shown in terms of strain, a quite satisfying match is nonetheless achieved for the interaction of temperature with the mean strain effect.  It is especially satisfying that such rich behavior is so compactly and so accurately described by means of the Mars-Fatemi crystallization parameter.

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My SAE WCX 2022 Top Takeaway

 

SAE WCX | Detroit, Michigan | April 5-7, 2022

There were several papers on fatigue life prediction for elastomers at SAE WCX 2022, but the highlight for us was this one from Automotive OEM Stellantis: “Fatigue Life Prediction and Correlation for Powertrain Torque Strut Mount Elastomeric Bushing Application” by Dr. Touhid Zarrin-Ghalami, Durability Technical Specialist at FCA US LLC Fiat Chrysler Automobiles logowith coauthors C Elango, Sathish Kumar Pandi, and Roshan N. Mahadule from FCA Engineering India Pvt, Ltd.  Check out the abstract or buy the paper here…

The study shows that very accurate fatigue life prediction results are possible for elastomeric components under block cycle loading using Critical Plane Analysis.  A key feature of the analysis is the characterization and modeling of rubber’s hyperelastic properties, fatigue crack growth properties, crack precursor size, and strain crystallization behavior.  Careful measurement of these analysis ingredients led to a nearly perfect correlation of the predicted life (520 blocks) with the tested life (523 blocks, average of 4 replicate tests), and of predicted failure mode with observed failure mode.

Endurica users like Stellantis are developing a solid track record of routine and successful fatigue life prediction.  We soon expect to see the day when CAE fatigue life prediction for rubber components is regarded as obligatory, given the risk and cost avoided with “right the first time” engineering.

Congratulations to the Stellantis team on this impressive success!

 Fatigue Life (block) demonstrating the accuracy of the CAE Virtual Simulation compared to a physical test

Citation: Elango, C., Pandi, S.K., Mahadule, R.N., and Zarrin-Ghalami, T., “Fatigue Life Prediction and Correlation of Engine Mount Elastomeric Bushing using A Crack Growth Approach,” SAE Technical Paper 2022-01-0760, 2022, doi:10.4271/2022-01-0760.

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Things that went right in 2020 at Endurica

Things that went right in 2020 at Endurica

2020 is burned in all our minds as a chaotic and tough year.  Just like the rest of the world, Endurica staff experienced times of isolation and loss due to the pandemic.  On a positive note, we invested heavily in making our tools and workflows better than ever so that we’re ready to come back strong in 2021.  Here is a list of our top new developments in 2020:

Endurica Software Enhancements

  • Endurica DT’s new Ageing Feature now enables you to simulate how ageing affects your rubber product. Your compound’s stiffness, strength, and fatigue properties can all evolve with time.
  • Our new Linux distribution takes our solutions beyond the Windows world.
  • We’ve added an encryption feature to safeguard your trade secrets.
  • Viewer Improvements make it easier than ever to visualize your fatigue simulation results.
  • EIE Enhancements give you blazing-fast compute speed for full road-load signals.
  • We’ve also planned an aggressive development agenda for 2021. Stay tuned for a new Endurica-based smartphone app for materials engineers, for a new feature that computes fatigue threshold safety margins, for a new block cycle schedule extraction algorithm, and more!

Training

  • The new Fatigue Ninja Friday webinar series provides step-by-step application training for key the workflows that you need to get durability right. All of the recorded episodes are now available in the online Endurica academy.
  • The new Winning on Durability webinar series provides high-level overviews of both technical and business topics so you can connect Endurica tools to your strategic imperatives. All of these recorded webinars are available gratis on our website.
  • We’ve recast our in-person training events as LIVE, ONLINE workshops accessible safely around the world.

Testing Instruments

Fatigue Property Mapping Testing Service

  • We added the Reliability Module to our Fatigue Property Mapping testing service. Use it to quantify crack precursor size statistics when you need to estimate probability of failure.
  • We also reorganized the Thermal Module and the Ageing Module into Basic and Advanced levels, to offer a lower price-point when a basic option will suffice.

Want to leverage any of these new capabilities in your next durability project?  Give us a call and let’s talk!

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Is It Validated?

Is it Validated?

“Is it validated?” – that’s often the first question we hear after introducing our durability simulation capabilities. And for good reason, given the weight that hangs on the hinge of product durability. Endurica takes verification and validation (V&V) very seriously. Let’s look at what that means.

First, it means that our tools are built on well-known, well-established foundations.  These foundations include 1) definition of material / crack behavior via fracture mechanics (Rivlin and Thomas, 1953), 2) integration of the crack growth rate law to predict fatigue life (Gent, Lindley and Thomas, 1964), 3) the fact that crack precursors occur naturally in all locations and all orientations in a rubber sample (Choi and Roland 1996, Huneau et al 2016), 4) hyperelastic stress-strain laws compatible with commercial FEA codes (see Muhr 2005 for an excellent review), and 5) rubber’s fatigue threshold (Lake and Thomas 1967).  The validation case thus begins with the cumulative authority of thousands of reports that have confirmed these classical results over nearly 70 years.

Critical plane analysis for rubber has now been around for 20+ years, and it has been validated in multiple ways (material level, component level, system level), across multiple experimental programs (industrial and academic), by multiple independent research groups working on multiple applications (see Google/scholar, for example).  It has been validated that: 1) it correctly predicts crack plane orientation under uniaxial, proportional and nonproportional loadings (Harbour et al 2008), 2) it correctly predicts fatigue life across different modes of deformation (Mars 2002), 3) it correctly accounts for the effects of crack closure (Mars 2002), 4) it correctly predicts the development of off-axis cracks for nonrelaxing cycles in strain-crystallizing materials (Ramachandran 2017), 5) it correctly predicts the effects of finite straining on crack orientation (Mars and Fatemi 2006).

The literature is full of old experiments that we have used as validation targets.  We have validated Endurica’s strain crystallization models by simulating experimental results published by Cadwell et al (1940) and by Fielding et al (1943).  We have validated the ability to predict deformation mode effects by simulating experimental results for simple and biaxial tension published by Roberts and Benzies (1977).  We have validated Endurica’s temperature dependence against measurements reported by Lake and Lindley (1964).  We have validated against multiaxial fatigue experiments reported by Saintier, Cailletaud and Piques (2006).

We’ve done our own validation experiments.  My PhD dissertation (University of Toledo, 2001) contains an extensive database of tension/torsion/compression fatigue tests against which our critical plane algorithms were validated.  Two additional PhD dissertations that I co-advised generated additional validations.  Dr. Malik Ait Bachir’s thesis (2010) validated mathematically that the scaling law we use for small cracks is valid across all multiaxial loading states.  Dr. Ryan Harbour’s thesis (2006) contains a database of multiaxial, variable amplitude fatigue experiments against which our rainflow and damage accumulation procedures were extensively validated.

Validation from partners.  We partner with several testing labs.  We have invested in testing protocols that produce clean, accurate data and we have run validation programs with our partners to verify the effectiveness of our testing protocols.  We’ve demonstrated significant improvements to test efficiency and reproducibility (Goosens and Mars 2018) and (Mars and Isasi 2019).  We’ve validated techniques for estimating precursor size and size distribution (Robertson et al 2020, Li et al 2015).

Validation from users.  Three (3) of the top 12 tire companies and six (6) of the top 10 global non-tire rubber companies now use our solutions.  Most of our users have run internal validation programs to show the effectiveness of our solutions for their applications.  Most of these studies are unpublished, but the fact that our user base has continued growing at ~20%/year for 12 years (as of this year) says something important both about the technical validation case and the business validation case.  Validation studies have been published with the US Army (Mars, Castanier, Ostberg 2017), GM (Barbash and Mars 2016), Tenneco (Goossens et al 2017) and Caterpillar (Ramachandran et al 2017).

Validation from external groups.  There are several academic groups that have independently applied and validated components of our approach.  There are too many to list completely, but a few recent examples include Zarrin-Ghalami et al (2020), Belkhira et al (2020) and Tobajas et al (2020).

Software verification, benchmarking and unit testing.  In addition to the experimental validations mentioned above, each time we build a new version of our software, we execute a series of automated tests.  These tests verify every line of code against expected function, and they ensure that as we add new features, we do not introduce unintended changes.  The benchmarks include tests that verify things like coordinate frame objectivity (rigid rotations under static load should do no damage and the same strain history written in two different coordinate systems should have the same life), and check known results pertaining to material models and cycle counting rules.  You can read more about our software quality processes here.

It is safe to say that no other solution for fatigue life prediction of rubber has been tested and validated against a larger number of applications than Endurica’s.

References

Aıt-Bachir, M. “Prediction of crack initiation in elastomers in the framework of Configurational Mechanics.” PhD diss., Ph. D. thesis, Ecole Centrale de Nantes, Nantes (France), 2010.

Barbash, Kevin P., and William V. Mars. Critical plane analysis of rubber bushing durability under road loads. No. 2016-01-0393. SAE Technical Paper, 2016.

Belkhiria, Salma, Adel Hamdi, and Raouf Fathallah. “Cracking energy density for rubber materials: Computation and implementation in multiaxial fatigue design.” Polymer Engineering & Science (2020).

Cadwell, S. M., R. A. Merrill, C. M. Sloman, and F. L. Yost. “Dynamic fatigue life of rubber.” Rubber Chemistry and Technology 13, no. 2 (1940): 304-315.

Choi, I. S., and C. M. Roland. “Intrinsic defects and the failure properties of cis-1, 4-polyisoprenes.” Rubber chemistry and technology 69, no. 4 (1996): 591-599.

Fielding, J. H. “Flex life and crystallization of synthetic rubber.” Industrial & Engineering Chemistry 35, no. 12 (1943): 1259-1261.

Goossens, J.R., Mars, W., Smith, G., Heil, P., Braddock, S. and Pilarski, J., 2017. Durability Analysis of 3-Axis Input to Elastomeric Front Lower Control Arm Vertical Ride Bushing (No. 2017-01-1857). SAE Technical Paper. https://doi.org/10.4271/2017-01-1857

Goossens, Joshua R., and William V. Mars. “Finitely Scoped, High Reliability Fatigue Crack Growth Measurements.” Rubber Chemistry and Technology 91, no. 4 (2018): 644-650. https://doi.org/10.5254/rct.18.81532

Harbour, Ryan Joseph. Multiaxial deformation and fatigue of rubber under variable amplitude loading. Vol. 67, no. 12. 2006.

Harbour, Ryan J., Ali Fatemi, and Will V. Mars. “Fatigue crack orientation in NR and SBR under variable amplitude and multiaxial loading conditions.” Journal of materials science 43, no. 6 (2008): 1783-1794.

Huneau, Bertrand, Isaure Masquelier, Yann Marco, Vincent Le Saux, Simon Noizet, Clémentine Schiel, and Pierre Charrier. “Fatigue crack initiation in a carbon black–filled natural rubber.” Rubber Chemistry and Technology 89, no. 1 (2016): 126-141.

Lake, G. J., and P. B. Lindley. “Cut growth and fatigue of rubbers. II. Experiments on a noncrystallizing rubber.” Journal of Applied Polymer Science 8, no. 2 (1964): 707-721.

Li, Fanzhu, Jinpeng Liu, W. V. Mars, Tung W. Chan, Yonglai Lu, Haibo Yang, and Liqun Zhang. “Crack precursor size for natural rubber inferred from relaxing and non-relaxing fatigue experiments.” International Journal of Fatigue 80 (2015): 50-57.

Mars, William Vernon. Multiaxial fatigue of rubber. 2001.

Mars, Will V. “Cracking energy density as a predictor of fatigue life under multiaxial conditions.” Rubber chemistry and technology 75, no. 1 (2002): 1-17.

Mars, W. V., and A. Fatemi. “Analysis of fatigue life under complex loading: Revisiting Cadwell, Merrill, Sloman, and Yost.” Rubber chemistry and technology 79, no. 4 (2006): 589-601.

Mars, W. V., and A. Fatemi. “Nucleation and growth of small fatigue cracks in filled natural rubber under multiaxial loading.” Journal of materials science 41, no. 22 (2006): 7324-7332.

Mars, W. V. “Computed dependence of rubber’s fatigue behavior on strain crystallization.” Rubber Chemistry and Technology 82, no. 1 (2009): 51-61. https://doi.org/10.5254/1.3557006

Mars, William V., Matthew Castanier, David Ostberg, and William Bradford. “Digital Twin for Tank Track Elastomers: Predicting Self-Heating and Durability.” In Proceedings of the 2017 Ground Vehicle Systems Engineering and Technology Symposium (GVSETS). 2017.pdf here

Mars, W. V., and M. Isasi. “Finitely scoped procedure for generating fully relaxing strain-life curves.” In Constitutive Models for Rubber XI: Proceedings of the 11th European Conference on Constitutive Models for Rubber (ECCMR 2019), June 25-27, 2019, Nantes, France, p. 435. CRC Press, 2019.

Muhr, A. H. “Modeling the stress-strain behavior of rubber.” Rubber chemistry and technology 78, no. 3 (2005): 391-425.Lake and Thomas 1967

Ramachandran, Anantharaman, Ross P. Wietharn, Sunil I. Mathew, W. V. Mars, and M. A. Bauman. “Critical Plane Selection Under Nonrelaxing Simple Tension with Strain Crystallization.” In Fall 192nd Technical Meeting of the Rubber Division, pp. 10-12. 2017.

Rivlin, R. S., and A. G. Thomas. “Rupture of rubber. I. Characteristic energy for tearing.” Journal of polymer science 10, no. 3 (1953): 291-318.Gent, Lindley and Thomas, 1964

Roberts, B. J., and J. B. Benzies. “The relationship between uniaxial and equibiaxial fatigue in gum and carbon black filled vulcanizates.” Proceedings of rubbercon 77, no. 2 (1977): 1-13.

Robertson, Christopher G., Lewis B. Tunnicliffe, Lawrence Maciag, Mark A. Bauman, Kurt Miller, Charles R. Herd, and William V. Mars. “Characterizing Distributions of Tensile Strength and Crack Precursor Size to Evaluate Filler Dispersion Effects and Reliability of Rubber.” Polymers 12, no. 1 (2020): 203. Pdf here

Saintier, Nicolas, Georges Cailletaud, and Roland Piques. “Multiaxial fatigue life prediction for a natural rubber.” International Journal of Fatigue 28, no. 5-6 (2006): 530-539.

Tobajas, Rafael, Daniel Elduque, Elena Ibarz, Carlos Javierre, and Luis Gracia. “A New Multiparameter Model for Multiaxial Fatigue Life Prediction of Rubber Materials.” Polymers 12, no. 5 (2020): 1194.

Zarrin-Ghalami, Touhid, Sandip Datta, Robert Bodombo Keinti, and Ravish Chandrashekar. Elastomeric Component Fatigue Analysis: Rubber Fatigue Prediction and Correlation Comparing Crack Initiation and Crack Growth Methodologies. No. 2020-01-0193. SAE Technical Paper, 2020.

 

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